The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / ClOOCl / McKeachie(2004)_223K_234-398nm

DATAFILE: ClOOCl_McKeachie(2004)_223K_234-398nm.txt
NAME: dichlorine dioxide, chlorine monoxide dimer, chlorine peroxide
FORMULA: ClOOCl
AUTHOR(YEAR): McKeachie(2004)
T: 223K
λ: 234-398nm
BIBLIOGRAPHY: J.R. McKeachie, M.F. Appel, U. Kirchner, R.N. Schindler, and T. Benter, "Observation of a heterogeneous source of OClO from the reaction of ClO radicals on ice", J. Phys. Chem. B 108, 16786-16796 (2004); DOI: 10.1021/jp049314p
COMMENTS: OClO + O radical source (dry flow tube) for the preparation of ClOOCl

The absorption spectrum was normalized to the JPL recommended spectrum given by

W.B. DeMore, S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, and M.J. Molina, "Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. Evaluation Number 12", JPL Publication 97-4, 1997

The numerical data corresponding to Figure 4 in the publication were obtained by personal communication from Marc von Hobe (Nov 2007)

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